The following develops a consistent approach, often called "error propagation,"
that makes it possible to determine the uncertainty characteristics in
derived quantities if the characteristics of the fundamental measurements
are known. Let
=
be a set of measured quantities with known measurement uncertainties.2.7
Consider derived quantities
=
,
each of which is a function of the measured quantities
:
| (2.15) |
The mean values of
,
,
are then the "best" values for
in the sense that they minimize the squares of the deviations from these
best values. In the same sense, the "best" values for Ym
are the values
.2.8
The one-standard-deviation uncertainties in
are those that represent the range over which
can vary while
remain
within one-standard-deviation of their measured values. For small deviations,
a first-order Taylor expansion relates deviations in
to deviations in
:
| (2.16) |
The variance in Ym is then obtained by averaging over the N measurements, indicated by index i:
| (2.17) |
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(2.18) |
| (2.19) |
The matrix elements
| (2.20) |
entering (2.16) are the variances and covariances of the measured quantities,
so
is called the covariance matrix or the error matrix. If the
relationship between
and
is
linear or is assumed linear (as in the first-order Taylor expansion) over
the range of fluctuations, then this matrix is particularly useful for
determining the variances in derived quantities because those variances
can be expressed as
| (2.21) |
![]() |
(2.22) |
or, in matrix notation,
| |
(2.23) |
where Tmj =
is the element of the (column) matrix of derivatives of the derived quantity
Ym with respect to the measured quantity xj
and the superscript t denotes the transpose matrix. This general
form is valid for any correlations among the original measurements (which
will be represented by off-diagonal elements of
)
and properly represents the correlations among dependent variables.

The thermocouple junctions both produce voltage differences, dependent
respectively on the temperature T and on the reference bath temperature
Tref. The reason for using this arrangement is that both
the wires leading to the instrument measuring the voltage V are
then copper wires, and can connect to copper junctions at the voltmeter
without introducing additional contact potentials such as would result
if the constantan wire were connected directly to the voltmeter. The uncertainty
in T is then caused by two sources: (a) the uncertainty in the measurement
of
= T-Tref, and (b) the uncertainty in Tref.
Often, a thermistor is used to measure the temperature of the reference
bath (or of a metal block used in the same way).
If a thermistor is used to determine the temperature of the reference
junction, as shown, there are two voltages that must be measured to determine
the unknown temperature T: V1, produced by the
pair of thermocouples, and V2, produced by the thermistor.
These are related to the temperature difference
=(T-Tref)
and to T2, the temperature of the thermistor junction,
by functions Y1 and Y2, which often
are almost linear relationships:
| (2.24) |
| T2 = Y2(V2) = a2 V2 . | (2.25) |
Then the first two fundamental quantities affecting the measurement, in the earlier notation, are x1=V1 and x2=V2.
If V1 and V2 are measured by the same voltmeter, part of the uncertainty in V2 will be correlated with that in V1because bias in the voltmeter will affect both measurements in the same way. This will be reflected in off-diagonal terms in the error matrix, representing correlations between errors in V1 and V2.
There will also be an error in the measurement of T introduced by the assumption that Tref=T2, because the temperature bath or constant-temperature block may not be uniform in temperature. Another function Y3=x3=Tref-T2 can be introduced to account for this error source, which probably will be a systematic error. The measurement T is then determined from
| (2.26) |
Suppose that the voltmeter has a precision of Si and a systematic error of Bi when measuring Vi, and that the random errors are uncorrelated but the bias errors are always the same (as might occur for a calibration error). If the only sources of error are these random and systematic errors and a non-zero value of Y3, the error matrix for the random component of the uncertainty is
![]() |
(2.27) |
and the bias component is
![]() |
(2.28) |
when expressed in terms of the fundamental quantities x1, x2, and x3 representing the two measurements and the unmeasured difference between Tref and T2.
The sum of these matrices can be used in (2.23) to evaluate the variance in the measured temperature:
![]() |
(2.29) |
| = a12S12+a22S22+(a1B1+a2B2)2+B32 . | (2.30) |
The first two terms show that the random contributions add to the net
variance in quadrature, as expected for independent error sources. The
next term shows that the bias contributions, however, add linearly. This
results because a bias error affects measurements of
and T2 in the same way, so the error enters the final
result additively.